Published April 1, 1982
| Version v1
Journal article
Simultaneous proton transfers coupled with heavy atom motion in the transition state of the 2-pyridone-catalysed mutarotation of tetramethylglucose
- 1. Uppsala Univ. (Sweden)
- 2. Rochester Univ., NY (USA). Dept. of Chemistry
Description
Primary and secondary deuterium isotope effects and calculated primary isotope effects for the 2-pyridone-catalysed mutarotation of tetramethylglucose suggest rate-limiting simultaneous transfer of two protons coupled with considerable heavy atom motion. (author)
Additional details
Additional titles
- Subtitle (English)
- Primary and secondary deuterium isotope effects
Publishing Information
- Journal Title
- J. Chem. Soc. (London), Chem. Commun.
- Journal Issue
- no.7
- Series
- J. Chem. Soc. (London), Chem. Commun.
- ISSN
- 0022-4936
INIS
- Country of Publication
- United Kingdom
- Country of Input or Organization
- United Kingdom
- INIS RN
- 13683097
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- ALDEHYDES; ALKANES; CATALYSIS; CHEMICAL REACTION KINETICS; CHEMICAL REACTIONS; DEUTERIUM; DEUTERIUM COMPOUNDS; HEXOSES; HYDROXY COMPOUNDS; ISOMERS; ISOTOPE EFFECTS; ISOTOPIC EXCHANGE; KETONES; OPTICAL ACTIVITY; PYRIDINES; STEREOCHEMISTRY
- Descriptors DEC
- AZINES; CARBOHYDRATES; HETEROCYCLIC COMPOUNDS; HYDROCARBONS; HYDROGEN COMPOUNDS; HYDROGEN ISOTOPES; ISOTOPES; KINETICS; LIGHT NUCLEI; MONOSACCHARIDES; NUCLEI; ODD-ODD NUCLEI; OPTICAL PROPERTIES; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; PHYSICAL PROPERTIES; REACTION KINETICS; SACCHARIDES; STABLE ISOTOPES