Simulated laser-induced breakdown spectra of graphite and synthetic shergottite glass under Martian conditions

Highlights: • Simulation of the LIBS spectra of graphite and synthetic shergottite glass under Mars conditions • Comparison of simulated and measured LIBS spectra under Mars ChemCam conditions • Effect of pressure and laser irradiance on LIBS spectra under Mars ChemCam conditions We report the results of a simulation of the laser-induced breakdown spectra of graphite and synthetic shergottite glass in an atmosphere similar to that of Mars using a 1-D, Lagrangian hydrodynamic model, a spherical geometry description of the laser ablation and plume expansion and a local thermodynamic equilibrium (LTE) approach for the emission spectra. We compare the LIBS spectra of two calibration targets on board of the Curiosity rover to the simulated ones calculated under nominally the same conditions as those encountered on Mars. The simulations provide an additional way, to laboratory based comparative studies, to better understand the effects of laser parameters and atmospheric pressures. We report on the effect of laser irradiance and ambient pressure on the electron and ion temperature, electron number density, and fluid velocity parameters characterizing the plasma. Finally, we show the effects of laser irradiance and ambient pressure on the simulated emission spectra of graphite and shergottite and compare them to those acquired by ChemCam. The agreement between the two is good, particularly for the prominent emission lines.