Published 1979
| Version v1
Journal article
Coordination of n-donor two-center ligands in tantalum complexes
- 1. AN SSSR, Moscow. Inst. Obshchej i Neorganicheskoj Khimii
Description
The 19F NMR technique was used to study the structure of tantalum fluoroximate complexes obtained by the interaction of acetoxime, benzalodoxime and ethylmethylketoxime with the acetonitryl solution of tantalum pentafluoride and by the reaction between tantalum pentaacetooximate and Et3NHF. The spectra were recorded over the temperature range from -30 to +30 deg. The 19F chemical shifts were determined with respect to CFCl3. The parameters of the spectra were reported
Additional details
Additional titles
- Original title (Russian)
- Координация н-донорных двухцентровых лигандов в комплексах тантала
Publishing Information
- Journal Title
- Dokl. Akad. Nauk SSSR
- Journal Volume
- 247
- Journal Issue
- 5
- Series
- Dokl. Akad. Nauk SSSR.
- Journal Page Range
- 1197-1201
- ISSN
- 0002-3264
INIS
- Country of Publication
- Russian Federation
- Country of Input or Organization
- USSR
- INIS RN
- 11557718
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- BINDING ENERGY; CHEMICAL COMPOSITION; CHEMICAL PREPARATION; CHEMICAL SHIFT; ELECTRONS; LIGANDS; LOW TEMPERATURE; MEDIUM TEMPERATURE; MOLECULAR STRUCTURE; NMR SPECTRA; OXIMES; TANTALUM COMPLEXES; TANTALUM FLUORIDES; VALENCE
- Descriptors DEC
- AMINES; COMPLEXES; ELEMENTARY PARTICLES; ENERGY; FERMIONS; FLUORIDES; FLUORINE COMPOUNDS; HALIDES; HALOGEN COMPOUNDS; HYDROXY COMPOUNDS; LEPTONS; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; SPECTRA; SYNTHESIS; TANTALUM COMPOUNDS; TRANSITION ELEMENT COMPLEXES; TRANSITION ELEMENT COMPOUNDS