Published November 20, 1982
| Version v1
Journal article
Study of Hg(I) complexes in Hg(II) solutions γ-irradiated at 770K
Description
The properties of some Hg(I) chloride complexes, and in particular the effect of ligands on the delocalization of the unpaired electron is the subject of this report. The formation of HgX (X = Cl, Br, I, Cn, CNS) as an intermediate short-lived particle was postulated during the pulse radiolysis of aqueous solutions of HgX2 salts. Results indicated that HgCl particles are formed during the γ-irradiation of aqueous H2SO4 and alcohol solutions of HgCl2, while HgCl43- particles are formed in the HCl solutions. Also the parameters of the EPR spectra and the optical characteristics of the particles were determined. The mechanisms of their formation are discussed
Additional details
Publishing Information
- Journal Title
- Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.)
- Journal Volume
- 31
- Journal Issue
- 5
- Series
- Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.).
- Journal Page Range
- 1060-1062
- ISSN
- 0568-5230
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 15016923
- Subject category
- S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
- Descriptors DEI
- CHEMICAL REACTION YIELD; GAMMA RADIATION; MERCURY CHLORIDES; MERCURY COMPOUNDS; RADIOLYSIS; REACTION INTERMEDIATES; SPECTRA
- Descriptors DEC
- CHEMICAL RADIATION EFFECTS; CHEMICAL REACTIONS; CHLORIDES; CHLORINE COMPOUNDS; DECOMPOSITION; ELECTROMAGNETIC RADIATION; HALIDES; HALOGEN COMPOUNDS; IONIZING RADIATIONS; RADIATION EFFECTS; RADIATIONS
Optional Information
- Notes
- Translated from Izv. Akad. Nauk SSSR, Ser. Khim.; No.5, 1187-1188(May 1982). Cover-to-cover translation of Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya (USSR).