Published April 1993
| Version v1
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Technetium complexes with thioether ligands. Pt. 3
Creators
- 1. Forschungszentrum Rossendorf e.V. (Germany)
- 2. Bundesanstalt fuer Materialforschung, Berlin (Germany)
Description
In order to gain an insight into the effects on coordination geometry and complex stabilities of factors such as ring size and functional group substituent in macrocyclic polythioether ligands, a number of technetium chelates with the thiacrown ethers 1,4,8,11-tetrathiacyclotetradecane (14S4), 1,5,9,13-tetrathiacyclohexadecane (16S4), 1,5,9,13-tetrathia-cyclohexadecane-3,11-diol (16S4-(OH)2) and 1,4,7,10,13,16-hexathiacyclooctadecane (18S6) were synthesized. Some representatives were characterized by X-ray crystal structure determination. (orig.)
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Additional details
Additional titles
- Subtitle (English)
- Synthesis and structural characterization of cationic technetium complexes with thiacrown ethers
Publishing Information
- Imprint Title
- Institute of Bioinorganic and Radiopharmaceutical Chemistry. Annual report 1992
- Imprint Pagination
- 144 p.
- Journal Page Range
- p. 73-81.
- Report number
- FZR--93-12
INIS
- Country of Publication
- Germany
- Country of Input or Organization
- Germany
- INIS RN
- 25063435
- Subject category
- S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
- Descriptors DEI
- BOND ANGLE; BOND LENGTHS; CATIONS; CHELATES; CHEMICAL PREPARATION; CROWN ETHERS; LIGANDS; STABILITY; STRUCTURAL CHEMICAL ANALYSIS; SULFIDES; TECHNETIUM COMPLEXES; X-RAY DIFFRACTION
- Descriptors DEC
- CHALCOGENIDES; CHARGED PARTICLES; COHERENT SCATTERING; COMPLEXES; DIFFRACTION; ETHERS; IONS; ORGANIC COMPOUNDS; ORGANIC OXYGEN COMPOUNDS; SCATTERING; SULFUR COMPOUNDS; SYNTHESIS; TRANSITION ELEMENT COMPLEXES