Published January 11, 1988
| Version v1
Journal article
Reactions of radical cations of acetals
- 1. Moskovskij Gosudarstvennyj Univ. (USSR). Khimicheskij Fakul'tet
Description
The thermal and photochemical reactions of the methylal radical cation in freon matrices were studied using selective deuteration for elucidating the structure of the resulting species. The methylal radical cation was shown to decay by unimolecular reaction upon heating to 140 K as well as upon photolysis in CFCl3 matrix and the product of decay is assumed to be the complex of formaldehyde radical cation with CFCl3. Such decay reaction was demonstrated for 1,3-dioxolan radical cation as well. (author) 15 refs.; 4 figs
Additional details
Additional titles
- Subtitle (English)
- Evidence for unimolecular decomposition
Publishing Information
- Journal Title
- J. Radioanal. Nucl. Chem.
- Journal Volume
- 126
- Journal Issue
- 1
- Series
- J. Radioanal. Nucl. Chem. ;Letters.
- Journal Page Range
- 39-51
- ISSN
- 0236-5731
- CODEN
- JRNCD
INIS
- Country of Publication
- Hungary
- Country of Input or Organization
- Hungary
- INIS RN
- 19087208
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
- Descriptors DEI
- CATIONS; COMPLEXES; DEUTERATION; ELECTRON SPIN RESONANCE; FORMYL RADICALS; FREONS; GAMMA RADIATION; METHYLAL; PHOTOLYSIS; RADIOLYSIS; STABILITY; STRUCTURAL CHEMICAL ANALYSIS
- Descriptors DEC
- ACYL RADICALS; CHARGED PARTICLES; CHEMICAL RADIATION EFFECTS; CHEMICAL REACTIONS; DECOMPOSITION; ELECTROMAGNETIC RADIATION; ETHERS; IONIZING RADIATIONS; IONS; MAGNETIC RESONANCE; ORGANIC COMPOUNDS; ORGANIC HALOGEN COMPOUNDS; ORGANIC OXYGEN COMPOUNDS; RADIATION EFFECTS; RADIATIONS; RADICALS; RESONANCE