Published July 1981 | Version v1
Journal article Metadata-only

Formation of adduct of cerium (4) thenoyltrifluoroacetonate

Creators

  • 1. Moskovskij Gosudarstvennyj Univ. (USSR)

Description

Adduct formation of thenoyltrifluoroacetonate of Ce(4) [Ce(TTFA)4] with seven nitrogen- and oxygen-containing donor additional ligands is studied using the methods of IR-spectroscopy, derivatography, X-ray phase analysis. The presence of formation of Ce(TTFA)4 adducts with phosphorus-containing additional ligands tributyl phosphate (TBP), trioctylphosphine oxide (TOPO), triphenylphosphine oxide (TPPO); α, α'-dipyridyl (Dipy) and o-phenanthroline (Phen) is established. The adduct Ce(TTFA)4 stable to reduction is formed with Dipy, and in the case of Phen, TBP, TOPO, TPPO in the process of adduct formation the reduction of Ce(4) to Ce(3) takes place

Additional details

Additional titles

Original title (Russian)
Аддуктообразование теноилтрифторацетонанта Cе(4)

Publishing Information

Journal Title
Izv. Akad. Nauk SSSR, Ser. Khim.
Journal Issue
no.7
Series
Izv. Akad. Nauk SSSR, Ser. Khim.
ISSN
0002-3353

INIS

Country of Publication
Russian Federation
Country of Input or Organization
USSR
INIS RN
13649928
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
ADDUCTS; CERIUM COMPLEXES; CHEMICAL PREPARATION; COORDINATION NUMBER; LIGANDS; PHENANTHROLINE-ORTHO; PYRIDINES; REDUCTION; TBP; TOPO; TPO; TTA
Descriptors DEC
AZINES; BUTYL PHOSPHATES; CHEMICAL REACTIONS; COMPLEXES; ESTERS; HETEROCYCLIC COMPOUNDS; KETONES; ORGANIC COMPOUNDS; ORGANIC FLUORINE COMPOUNDS; ORGANIC HALOGEN COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; ORGANIC PHOSPHORUS COMPOUNDS; ORGANIC SULFUR COMPOUNDS; PHENANTHROLINES; PHOSPHORIC ACID ESTERS; RARE EARTH COMPLEXES; REAGENTS; SYNTHESIS

Optional Information

Notes
For English translation see the journal Bulletin of the Academy of Sciences USSR, Division of Chemical Science (USA).