Published March 1997 | Version v1
Journal article Metadata-only

Chiroptical properties and structures of gyrotropic crystals of uranyl propionates

Creators

  • 1. Moskovskij Fiziko-Tekhnicheskij Inst., Moscow (Russian Federation)
  • 2. RAN, Moscow (Russian Federation). Inst. Obshchej i Neorganicheskoj Khimii

Description

Structure of optically active cubic crystals of cesium, rubidium, ammonium and thallium uranyl propionates isostructural to a certain crystal of sodium uranyl acetate with unique chiroptical features of crystals are not determined unambiguously only by 1-st coordination sphere of uranyl. In case of all-symmetric vibron transitions of fluorescent series one proved qualitatively the effect of extra-sphere cation on the values of rotation forces of the respective bands. Similar correlation is not observed in case all-symmetric vibron bands of uranyl other electron transitions. 10 refs., 3 figs., 7 tabs

Additional details

Additional titles

Original title (Russian)
Хироптические свойства и структура гиротропных кристаллов уранилпропионатов

Publishing Information

Journal Title
Zhurnal Neorganicheskoj Khimii
Journal Volume
42
Journal Issue
3
Journal Page Range
p. 391-395.
ISSN
0044-457X
CODEN
ZNOKAQ

INIS

Country of Publication
Russian Federation
Country of Input or Organization
Russian Federation
INIS RN
28060814
Subject category
S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY; S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
ALKALI METAL COMPOUNDS; AMMONIUM COMPOUNDS; BOND ANGLE; BOND LENGTHS; CRYSTALS; CUBIC LATTICES; ELECTRON DENSITY; ENERGY-LEVEL TRANSITIONS; INTERATOMIC DISTANCES; LATTICE PARAMETERS; MONOCARBOXYLIC ACIDS; SPACE GROUPS; URANYL COMPLEXES
Descriptors DEC
ACTINIDE COMPLEXES; CARBOXYLIC ACIDS; COMPLEXES; CRYSTAL LATTICES; CRYSTAL STRUCTURE; DISTANCE; ORGANIC ACIDS; ORGANIC COMPOUNDS; SYMMETRY GROUPS; URANIUM COMPLEXES