Published 1985 | Version v1
Journal article Metadata-only

Crystal structure of guanidonium heptafluorozirconate

Creators

  • 1. AN SSSR, Vladivostok. Inst. Khimii

Description

X-ray structural study of (CH3H6)3ZrF7 (diffractometer, MoKsub(α), least square method in anisotropic approximation, 1048 reflections, R=0.034) has been carpied out, the crystals are rhombic: a=12.644 (1), b=11.438 (1), c=10.021 (1)A, Z=4, sp. gr. Pbcn. The structure of (CN3H6)3-- ZrF7 is formed by monomeric complex anions [ZrF7]3- and cations (CN3H6)+. Coordination polyhedron of Zr presents a somewhat distorted one-cap trigonal prism, all the vertices of which are occupied by fluorine atoms. The structure of the compound and the system of hydrogen bonds in it are discussed

Additional details

Additional titles

Original title (Russian)
Кристаллическая структура гептафтороцирконата гуадония

Publishing Information

Journal Title
Koord. Khim.
Journal Volume
11
Journal Issue
4
Series
Koord. Khim.
Journal Page Range
566-569
ISSN
0132-344X
CODEN
KOKHD

INIS

Country of Publication
Russian Federation
Country of Input or Organization
USSR
INIS RN
17015534
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
BOND ANGLE; CHEMICAL BONDS; FLUORIDES; GUANIDINES; INTERATOMIC DISTANCES; LATTICE PARAMETERS; MOLECULAR STRUCTURE; ORTHORHOMBIC LATTICES; SPACE GROUPS; ZIRCONIUM COMPLEXES
Descriptors DEC
CARBONIC ACID DERIVATIVES; COMPLEXES; CRYSTAL LATTICES; CRYSTAL STRUCTURE; DISTANCE; FLUORINE COMPOUNDS; HALIDES; HALOGEN COMPOUNDS; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; SYMMETRY GROUPS; TRANSITION ELEMENT COMPLEXES