Identification of radicals in radiolysis of polychlorine-containing compounds

With the help of spin traps in polychloralkanes CCl4, CHCl3, CH2Cl2, 1.2-dichlorathene, as well in freons CCl2FCClF2 and CCl3CF3, irradiated with γ-rays in the liquid phase identified ares short-lived radicals: Cl atoms and radicals, arizing during the Cl atom detachment, i.e. CCl3, CHCl2, CH2Cl etc. or during C-C bond break in CCl3CF3(CCl3 and CF3)