Published May 2003 | Version v1
Journal article Metadata-only

A new lead Mo(IV) phosphate with a tunnel structure: Pb2Mo2O(PO4)2P2O7

Creators

Description

A molybdenum (IV) phosphate containing lead, Pb2Mo2(PO4)2P2O7, has been synthesized for the first time. It crystallizes in the space group C2/c with a=14.098(1) A, b=14.187(2) A, c=6.5592(4) A and β=102.08(1) deg. . Its original tunnel structure, built up of Mo2O11 bioctahedra, P2O7 and PO4 phosphate groups can be described from the assemblage of [Mo4P4O24] ∞ ribbons interconnected through monophosphate groups. The stereoactivity of the 6s2 lone pair of Pb2+, which is surrounded by nine oxygen atoms, is discussed

Additional details

Identifiers

PII
S0022459603000185;

Publishing Information

Journal Title
Journal of Solid State Chemistry
Journal Volume
172
Journal Issue
2
Journal Page Range
p. 412-416
ISSN
0022-4596
CODEN
JSSCBI

INIS

Country of Publication
United States
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
35002308
Subject category
S36: MATERIALS SCIENCE;
Descriptors DEI
CRYSTAL STRUCTURE; LATTICE PARAMETERS; LEAD COMPOUNDS; MOLYBDENUM COMPOUNDS; PHOSPHATES; SYNTHESIS
Descriptors DEC
OXYGEN COMPOUNDS; PHOSPHORUS COMPOUNDS; REFRACTORY METAL COMPOUNDS; TRANSITION ELEMENT COMPOUNDS

Optional Information

Copyright
Copyright (c) 2003 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.