Published March 10, 1986
| Version v1
Journal article
Transformations of some derivatives of 2-methoxycarbonylmethyl-4-hydroxy-2-cyclopenten-1-one
Creators
- 1. Institute of Organic Synthesis, Riga, USSR
Description
2-Methoxycarbonylmethyl-4-acyloxy-2-cyclopenten-1-ones are stable in an acidic medium, and hydrolysis of their ester group takes place with high yields. The action of nucleophilic agents leads to cleavage of the 2-methoxycarbonylmethyl-4-acyloxy-2-cyclopenten-1-ones with the elimination of the arene(alkane)-carboxylic acid and the formation of methyl 2-oxo-3(4)-cyclopentenylideneacetates
Additional details
Publishing Information
- Journal Title
- J. Org. Chem. USSR (Engl. Transl.)
- Journal Volume
- 21
- Journal Issue
- 10
- Series
- J. Org. Chem. USSR (Engl. Transl.).
- Journal Page Range
- 1914-1923
- ISSN
- 0022-3271
- CODEN
- JOCYA
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 19007687
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; S74: ATOMIC AND MOLECULAR PHYSICS;
- Descriptors DEI
- ACETATES; CARBOXYLIC ACIDS; CHEMICAL BONDS; CHEMICAL REACTION YIELD; CHEMICAL SHIFT; CHLOROFORM; COUPLING CONSTANTS; DECOMPOSITION; DEUTERIUM COMPOUNDS; ELECTRONIC STRUCTURE; HYDROGEN TRANSFER; HYDROGEN 1; HYDROXY COMPOUNDS; HYPERFINE STRUCTURE; INFRARED SPECTRA; ISOMERIZATION; ISOTOPIC EXCHANGE; J-J COUPLING; KETONES; MASS SPECTRA; MOLECULAR STRUCTURE; NMR SPECTRA; OVERHAUSER EFFECT; PROSTAGLANDINS; SYNTHESIS
- Descriptors DEC
- CARBOXYLIC ACID SALTS; CHEMICAL REACTIONS; COUPLING; HYDROGEN COMPOUNDS; HYDROGEN ISOTOPES; INTERMEDIATE COUPLING; ISOTOPES; LIGHT NUCLEI; NUCLEI; ODD-EVEN NUCLEI; ORGANIC ACIDS; ORGANIC CHLORINE COMPOUNDS; ORGANIC COMPOUNDS; ORGANIC HALOGEN COMPOUNDS; SPECTRA; STABLE ISOTOPES
Optional Information
- Notes
- Translated from Zh. Org. Khim.; 21: No.10, 2091-2101(Oct 1985).