Published November 15, 1976
| Version v1
Journal article
Vibronic coupling of pyridine in the nπ* excited state
Creators
- 1. Department of Chemistry, Faculty of Science, Tohoku University, Sendai, Japan
Description
The electronic absorption spectra and Raman spectra of pyridine and pyridine-d5 were measured. The vibrational analysis of the nπ* absorption spectrum and the preresonance Raman effect showed that the CH out-of-plane bending vibration ν10/sub a/(a2) (of the ground and excited-state frequencies 886 and 331 cm-1 for pyridine) is responsible for the vibronic coupling between the lowest nπ* state and the second lowest ππ* state
Additional details
Identifiers
- DOI
- 10.1063/1.432874;
Publishing Information
- Journal Title
- The Journal of Chemical Physics
- Journal Volume
- 65
- Journal Issue
- 10
- Series
- J. Chem. Phys.
- Journal Page Range
- 4163-4169
- ISSN
- 0021-9606
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 8292417
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- ABSORPTION SPECTRA; COUPLING; DEUTERIUM; EXCITED STATES; ISOTOPE EFFECTS; PYRIDINES; RAMAN EFFECT; VIBRATIONAL STATES
- Descriptors DEC
- AZINES; ENERGY LEVELS; HETEROCYCLIC COMPOUNDS; HYDROGEN ISOTOPES; ISOTOPES; LIGHT NUCLEI; NUCLEI; ODD-ODD NUCLEI; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; SPECTRA; STABLE ISOTOPES
Optional Information
- Notes
- Updated automatically by Metadata and Full-Text Enrichment Agent