Published 1985 | Version v1
Miscellaneous Open

Theoretical studies on CH+ ion molecule using configuration interaction method and its spectroscopic properties

Description

The use of the configuration (CI) method for the calculation of very accurate potential energy curves and dipole moment functions, and then their use in the comprehension of spectroscopic properties of diatomic molecules is presented. The spectroscopic properties of CH+ and CD+ such as: vibrational levels, spectroscopic constants, averaged dipole moments for all vibrational levels, radiative transition probabilities for emission and absorption, and radiative lifetimes are verificated. (M.J.C.)

Availability note (English)

MF available from INIS under the Report Number.

Abstract (Portuguese)

Apresenta-se a utilizacao do metodo interacao deconfiguracoes (CI) para se obter curvas de potencial e funcoes momentos de dipolo com elevada exatidao e usa-las na compreensao de propriedades espectroscopicas do CH+ e CD+ tais como: niveis vibracionais, constantes espectroscopicas, momentos dipolares medios para cada nivel vibracional, probabilidades de transicao para emissao e absorcao e tempos de vida radiativo. (M.J.C.)

Files

20064627.pdf

Files (2.2 MB)

Name Size Download all
md5:995a53899a53b63d418e167d1b4dbc7f
2.2 MB Preview Download

Additional details

Additional titles

Original title (Portuguese)
Estudos teoricos da molecula ion CH

Publishing Information

Imprint Pagination
146 p.
Report number
INIS-BR--1593

INIS

Country of Publication
Brazil
Country of Input or Organization
Brazil
INIS RN
20064627
Subject category
S74: ATOMIC AND MOLECULAR PHYSICS;
Resource subtype / Literary indicator
Thesis
Descriptors DEI
CONFIGURATION INTERACTION; DIPOLE MOMENTS; ELECTRONIC STRUCTURE; MOLECULAR ORBITAL METHOD; MOLECULES; RADIATIVE DECAY; SPECTROSCOPY; VIBRATIONAL STATES
Descriptors DEC
DECAY; ENERGY LEVELS; EXCITED STATES; PARTICLE DECAY