Published 1976
| Version v1
Journal article
Complexes of technetium(IV) and (III) with tertiary phosphines
- 1. Consiglio Nazionale delle Ricerche, Padua (Italy). Lab. di Chimica e Tecnologia dei Radioelementi
Description
The synthesis and characterization of the complexes trans-TcX4L2 and mer-TcX3L3(X = Cl and Br, and L = PMe2Ph, PEt2Ph and PPh3) are reported. Configurations were deduced by far-IR and 1H NMR studies. Magnetic susceptibility and 1H NMR results for mer-TcCl3(PMe2Ph)3 are compared with those for analogues d4 complexes. (author)
Additional details
Identifiers
Publishing Information
- Journal Title
- Journal of Inorganic and Nuclear Chemistry
- Journal Volume
- 38
- Journal Issue
- 4
- Series
- J. Inorg. Nucl. Chem.
- Journal Page Range
- 721-725
- ISSN
- 0022-1902
INIS
- Country of Publication
- United Kingdom
- Country of Input or Organization
- United Kingdom
- INIS RN
- 7243959
- Subject category
- S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
- Descriptors DEI
- CHEMICAL PREPARATION; FAR INFRARED RADIATION; INFRARED SPECTRA; MAGNETIC SUSCEPTIBILITY; MOLECULAR STRUCTURE; NUCLEAR MAGNETIC RESONANCE; ORGANIC PHOSPHORUS COMPOUNDS; PHOSPHINES; STRUCTURAL CHEMICAL ANALYSIS; TECHNETIUM COMPLEXES
- Descriptors DEC
- COMPLEXES; ELECTROMAGNETIC RADIATION; INFRARED RADIATION; MAGNETIC PROPERTIES; MAGNETIC RESONANCE; ORGANIC COMPOUNDS; PHOSPHORUS COMPOUNDS; PHYSICAL PROPERTIES; RADIATIONS; RESONANCE; SPECTRA; SYNTHESIS; TRANSITION ELEMENT COMPLEXES
Optional Information
- Notes
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