Preparation of nitrogen self-doped hierarchical porous carbon with rapid-freezing support for cooperative pollutant adsorption and catalytic oxidation of persulfate

Highlights: • The prepared catalyst has excellent PMS activation performance. • The prepared catalyst has strong adsorption performance. • Degradation of pollutants through mediated electron transfer mechanism. • The factors affecting the degradation efficiency are discussed. Herein, we report a method to synthesize nitrogen self-doped hierarchical porous carbon materials derived from chitosan. This method uses potassium hydroxide (KOH) activation and rapid-freezing technology. The catalyst (CA-900Q 1–1) obtained after rapid-freezing and KOH activation treatment show excellent persulfate activation ability. It can remove 20 mg bisphenol A (BPA) within 10 min better than traditional metal oxidate and nanomaterials. In the aquatic environment, CA-900Q 1–1 has a high resistance to inorganic anions. CA-900Q 1–1, possessing a high proportion of graphitic nitrogen, provides a sufficient number of active sites for persulfate activation. In addition, the catalyst yielded sizeable specific surface areas (SSAs) (1756.1 m²/g) and a hierarchical pore structure, which helps to improve the mass transfer in the carbon framework. The efficient adsorption of pollutants by the catalyst shortens the time required for target organic molecules to migrate to the catalyst surface and hierarchical pore structure. Furthermore, the catalyst has excellent electrical conductivity (R = 1.73 Ω), which enables pollutants adsorbed on the catalyst surface to transfer electrons to the persulfate through the N-doped sp²-hybrid carbon network faster.