Published October 1975
| Version v1
Journal article
Hot atom chemistry of tetramethylsilane
Description
Chemical behavior of recoiled 31Si atom produced by the 30Si(n,γ)31Si reaction of tetramethyl-silane in a reactor was studied and the results obtained were compared with those of pyrolysis. The effects of irradiation time and the quality of irradiation vessels on recoil products were also investigated. The recoiled 31Si atoms tend to recombine with methyl radicals by the effects of radical cage. Main recoil products were Me3SiOMe, Me3SiOH and dimers. The Si-Si and Si-C-Si bonds were formed by the recoil reaction as well as pyrolysis. It was found that quartz used as an irradiation capsule contributed to form the Si-O bond in recoil products. (auth.)
Additional details
Publishing Information
- Journal Title
- Annu. Rep. Res. React. Inst., Kyoto Univ.
- Journal Volume
- 8
- Series
- Annu. Rep. Res. React. Inst., Kyoto Univ.
- Journal Page Range
- 26-31
INIS
- Country of Publication
- Japan
- Country of Input or Organization
- Japan
- INIS RN
- 7272497
- Subject category
- S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
- Resource subtype / Literary indicator
- Progress Report
- Descriptors DEI
- CHEMICAL BONDS; CHEMICAL REACTION KINETICS; HOT ATOM CHEMISTRY; NEUTRON REACTIONS; RECOILS; SILANES; SILICON 31; TIME DEPENDENCE
- Descriptors DEC
- BARYON REACTIONS; BETA DECAY RADIOISOTOPES; BETA-MINUS DECAY RADIOISOTOPES; CHEMISTRY; EVEN-ODD NUCLEI; HADRON REACTIONS; HOURS LIVING RADIOISOTOPES; HYDRIDES; HYDROGEN COMPOUNDS; ISOTOPES; KINETICS; LIGHT NUCLEI; NUCLEAR REACTIONS; NUCLEI; NUCLEON REACTIONS; RADIOCHEMISTRY; RADIOISOTOPES; REACTION KINETICS; SILICON COMPOUNDS; SILICON ISOTOPES