Published May 1988 | Version v1
Journal article Metadata-only

Pulse radiolysis study of kinetics of palladium(2) oxidation by inorganic free radicals in acid aqueous solutions

Creators

  • 1. AN SSSR, Moscow. Inst. Fizicheskoj Khimii

Description

The method of pulse radiolysis (electrons, 5 MeV) has been applied to measure the constants of Pd(2) ion oxidation rates with OH radical, NO3 radical and SO4 radical in aqueous HNO3 and H2SO4 solutions. It is shown that the intraspheric mechanism of electron transfer including radical addition to Pd(2) ions in the axis perpendicular to the plane of aquaion square takes place in reactions studied

Additional details

Additional titles

Original title (Russian)
Исследование кинетики окисления палладия(2) неорганическими свободными радикалами в кислых водных растворах методом импульсного радиолиза

Publishing Information

Journal Title
Izv. Akad. Nauk SSSR, Ser. Khim.
Journal Issue
no.5
Series
Izv. Akad. Nauk SSSR, Ser. Khim.
ISSN
0002-3353
CODEN
IASKA

INIS

Country of Publication
Russian Federation
Country of Input or Organization
USSR
INIS RN
19103944
Subject category
S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
Descriptors DEI
AQUEOUS SOLUTIONS; CHEMICAL RADIATION EFFECTS; CHEMICAL REACTION KINETICS; ELECTRON BEAMS; MEV RANGE 01-10; NITRIC ACID; OXIDATION; PALLADIUM COMPOUNDS; PULSES; RADICALS; SULFURIC ACID
Descriptors DEC
BEAMS; CHEMICAL REACTIONS; DISPERSIONS; ENERGY RANGE; HOMOGENEOUS MIXTURES; HYDROGEN COMPOUNDS; INORGANIC ACIDS; INORGANIC COMPOUNDS; KINETICS; LEPTON BEAMS; MEV RANGE; MIXTURES; NITROGEN COMPOUNDS; OXYGEN COMPOUNDS; PARTICLE BEAMS; RADIATION EFFECTS; REACTION KINETICS; SOLUTIONS; SULFUR COMPOUNDS; TRANSITION ELEMENT COMPOUNDS