Published July 1983 | Version v1
Journal article Metadata-only

Adsorption of aliphatic hydrocarbons C6 on the Pd - Ru alloy

Creators

  • 1. Universitet Druzhby Narodov, Moscow (USSR)
  • 2. AN SSSR, Moscow. Inst. Neftekhimicheskogo Sinteza

Description

Chromatographic method was used to investigate into reversible adsorption of hexane, hexene-1 and hexadiene-1.5 on palladium alloy with 6% of ruthenium in 275-360 K range. Complex character of adsorption isobars of these hydrocarbons on the alloy reveals several forms of hydrocarbon chemisorption in investigated temperature range. Hydrogen affects substantially adsorption of n. hexane on the alloy: with increase of partial hydrogen pressure adsorption reduces on α-phase of alloy-hydrogen system and increases on β-phase. Adsorption and catalytic centers of alloy surface differ sufficiently

Additional details

Additional titles

Original title (Russian)
Адсорбция алифатических углеводородов C

Publishing Information

Journal Title
Izv. Akad. Nauk SSSR, Ser. Khim.
Journal Issue
no.7
Series
Izv. Akad. Nauk SSSR, Ser. Khim.
ISSN
0002-3353

INIS

Country of Publication
Russian Federation
Country of Input or Organization
USSR
INIS RN
15030539
Subject category
S36: MATERIALS SCIENCE;
Descriptors DEI
ADSORPTION; CATALYSTS; DIENES; HEXANE; HEXENES; ISOTHERMS; MEDIUM TEMPERATURE; PALLADIUM BASE ALLOYS; RUTHENIUM ALLOYS
Descriptors DEC
ALKANES; ALKENES; ALLOYS; HYDROCARBONS; ORGANIC COMPOUNDS; PALLADIUM ALLOYS; POLYENES

Optional Information

Notes
For English translation see the journal Bulletin of the Academy of Sciences USSR, Division of Chemical Science (USA).