Published February 1980
| Version v1
Journal article
Thermodynamic study of interaction in molybdenum and tungsten hexacarbonyl system
Description
By statistical method with membrane zero-manometer in the wide range of temperatures, pressures and compositions in the CO presence studied is the interaction in the double system of molybdenum and tungsten hexacarbonyls. The complex formation of compounds with a formally zero-valent atom of metal is noted, that explains the deviation from the Raoult's law. Thermodynamic characteristics of the summary process of carboxyl sublimation are established
Additional details
Additional titles
- Original title (Russian)
- Термодинамическое изучение взаимодействия в гексакарбонильной системе молибдена и вольфрама
Publishing Information
- Journal Title
- Zh. Fiz. Khim.
- Journal Volume
- 54
- Journal Issue
- 2
- Series
- Zh. Fiz. Khim.
- Journal Page Range
- 338-340
- ISSN
- 0044-4537
INIS
- Country of Publication
- Russian Federation
- Country of Input or Organization
- USSR
- INIS RN
- 11564518
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- CARBON MONOXIDE; CARBONYLS; COMPLEXES; ENTROPY; HIGH TEMPERATURE; LOW PRESSURE; MEDIUM TEMPERATURE; MOLYBDENUM COMPOUNDS; POLYMERIZATION; PRESSURE DEPENDENCE; QUANTITY RATIO; SUBLIMATION HEAT; TEMPERATURE DEPENDENCE; TUNGSTEN COMPOUNDS; VAPOR PRESSURE; VAPORS
- Descriptors DEC
- CARBON COMPOUNDS; CARBON OXIDES; CHALCOGENIDES; CHEMICAL REACTIONS; ENTHALPY; FLUIDS; GASES; OXIDES; OXYGEN COMPOUNDS; PHYSICAL PROPERTIES; THERMODYNAMIC PROPERTIES; TRANSITION ELEMENT COMPOUNDS; TRANSITION HEAT
Optional Information
- Notes
- For English translation see the journal Russian Journal of Physical Chemistry (UK).