Published July 2009
| Version v1
Journal article
Photophysical analysis of the organic complex [Eu(C12H8N2)2](NO3)3
- 1. Department of Materials Science, University of Milano-Bicocca, Via Roberto Cozzi 53, I-20125 Milano (Italy)
- 2. Department of Chemistry and Industrial Chemistry, University of Genoa, Via Dodecaneso 31, I-16146 Genoa (Italy)
Description
We have determined the photophysical properties of [Eu(C12H8N2)2](NO3)3, (EuPhen), a complex which is very promising for photonic and optoelectronic applications, because of its easy synthetic procedure and high thermal stability (up to 300 deg. C) combined with large sensitization efficiency and good emission quantum yield. Available experimental absorption and emission data have been analyzed by using Judd-Ofelt analysis. Moreover, semi-empirical calculations have been used to determine the structure of the complex and to interpret the convoluted shape of the absorption spectrum.
Availability note (English)
Available from http://dx.doi.org/10.1016/j.jlumin.2009.02.007Additional details
Identifiers
- DOI
- 10.1016/j.jlumin.2009.02.007;
- PII
- S0022-2313(09)00050-7;
Publishing Information
- Journal Title
- Journal of Luminescence
- Journal Volume
- 129
- Journal Issue
- 7
- Journal Page Range
- p. 746-750
- ISSN
- 0022-2313
- CODEN
- JLUMA8
INIS
- Country of Publication
- Netherlands
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 41112740
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; S36: MATERIALS SCIENCE;
- Descriptors DEI
- ABSORPTION SPECTRA; EFFICIENCY; EUROPIUM COMPLEXES; LUMINESCENCE; NITRATES; STABILITY; TEMPERATURE RANGE 0400-1000 K
- Descriptors DEC
- COMPLEXES; EMISSION; NITROGEN COMPOUNDS; OXYGEN COMPOUNDS; PHOTON EMISSION; RARE EARTH COMPLEXES; SPECTRA; TEMPERATURE RANGE
Optional Information
- Copyright
- Copyright (c) 2009 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.