Published July 2009 | Version v1
Journal article

Photophysical analysis of the organic complex [Eu(C12H8N2)2](NO3)3

  • 1. Department of Materials Science, University of Milano-Bicocca, Via Roberto Cozzi 53, I-20125 Milano (Italy)
  • 2. Department of Chemistry and Industrial Chemistry, University of Genoa, Via Dodecaneso 31, I-16146 Genoa (Italy)

Description

We have determined the photophysical properties of [Eu(C12H8N2)2](NO3)3, (EuPhen), a complex which is very promising for photonic and optoelectronic applications, because of its easy synthetic procedure and high thermal stability (up to 300 deg. C) combined with large sensitization efficiency and good emission quantum yield. Available experimental absorption and emission data have been analyzed by using Judd-Ofelt analysis. Moreover, semi-empirical calculations have been used to determine the structure of the complex and to interpret the convoluted shape of the absorption spectrum.

Availability note (English)

Available from http://dx.doi.org/10.1016/j.jlumin.2009.02.007

Additional details

Identifiers

DOI
10.1016/j.jlumin.2009.02.007;
PII
S0022-2313(09)00050-7;

Publishing Information

Journal Title
Journal of Luminescence
Journal Volume
129
Journal Issue
7
Journal Page Range
p. 746-750
ISSN
0022-2313
CODEN
JLUMA8

INIS

Optional Information

Copyright
Copyright (c) 2009 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.