Published January 1, 2006 | Version v1
Journal article Metadata-only

High-Pressure Synthesis and Structure Determination of K6(SeO4)(SeO5), The First Potassium Orthoselenate(VI)

Creators

Description

The authors report on the first synthesis of a potassium orthoselenate(VI), K6(SeO4)(SeO5), and the structure determination from synchrotron powder diffraction data. The title compound crystallizes in the tetragonal space group P41212 with a = 8.1259(1) (angstrom), c = 17.4953(2) (angstrom), V = 1155.21(2) (angstrom)3, and Z = 4. Selenium displays two different complex anions, tetrahedral SeO42- and trigonal-bipyramidal SeO54-. When the formula is reduced to A3B, the spatial arrangement of the constituting building units can be derived from the Li3Bi type of structure

Additional details

Identifiers

DOI
10.1021/ic061548v;

Publishing Information

Journal Title
Inorganic Chemistry
Journal Volume
45
Journal Page Range
p. 10947-10950
ISSN
0020-1669
CODEN
INOCAJ

INIS

Country of Publication
United States
Country of Input or Organization
United States
INIS RN
40002585
Subject category
S36: MATERIALS SCIENCE;
Descriptors DEI
ANIONS; DATA; DIFFRACTION; POTASSIUM; POWDERS; PRESSURE RANGE MEGA PA 10-100; SELENIUM; SPACE GROUPS; SYNCHROTRONS; SYNTHESIS
Descriptors DEC
ACCELERATORS; ALKALI METALS; CHARGED PARTICLES; COHERENT SCATTERING; CYCLIC ACCELERATORS; ELEMENTS; INFORMATION; IONS; METALS; PRESSURE RANGE; PRESSURE RANGE MEGA PA; SCATTERING; SEMIMETALS; SYMMETRY GROUPS

Optional Information

Contract/Grant/Project number
AC02-98CH10886
Notes
doi 10.1021/ic061548v
Funding organization
DS (US)
Secondary number(s)
BNL--80841-2008-JA