Published March 2000
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Static and dynamic structures of halogenated dimethyl ether radical cations: an ESR and MO study
- 1. Hiroshima Univ. (Japan). Faculty of Engineering
Description
An Electron Spin Resonance (ESR) study was carried out to elucidate static and dynamic structures of some halogenated dimethyl ether radical cations (CH3OCH2X+ and CH2XOCH2X+, X=F or Cl) generated in halocarbon matrices by γ-rays irradiation at 77 K. The ESR hf structures were successfully identified with the help of selectively deuterated compounds. (author)
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Additional details
Publishing Information
- Imprint Title
- Proceedings of the 8th Japan-China bilateral symposium on radiation chemistry
- Imprint Pagination
- 352 p.
- Journal Page Range
- p. 42-44
- Report number
- JAERI-Conf--2000-001
Conference
- Title
- 8. Japan-China bilateral symposium on radiation chemistry
- Acronym
- JCBSRC'99
- Dates
- 25-29 Oct 1999
- Place
- Kyoto (Japan)
INIS
- Country of Publication
- Japan
- Country of Input or Organization
- Japan
- INIS RN
- 31049652
- Subject category
- S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
- Resource subtype / Literary indicator
- Conference
- Descriptors DEI
- CATIONS; DEUTERIDES; ELECTRON SPIN RESONANCE; GAMMA RADIATION; HALOGENATION; IRRADIATION; METHYL ETHER; RADICALS; SPECTRA; TEMPERATURE DEPENDENCE
- Descriptors DEC
- CHARGED PARTICLES; CHEMICAL REACTIONS; DEUTERIUM COMPOUNDS; ELECTROMAGNETIC RADIATION; ETHERS; HYDROGEN COMPOUNDS; IONIZING RADIATIONS; IONS; MAGNETIC RESONANCE; ORGANIC COMPOUNDS; ORGANIC OXYGEN COMPOUNDS; RADIATIONS; RESONANCE
Optional Information
- Notes
- 3 refs., 2 figs., 1 tab.