Modeling the effects of temperature on the migration and transformation of nitrate during riverbank filtration using HYDRUS-2D

Highlights: • Denitrifcication rate constant was exponential with temperature during riverbank filtration. • An empirical formula between denitrification rate constant and temperature was developed in riverbank infiltration system. • Nitrate removal mainly occurred in the riparian zone during riverbank filtration. • Seasonal and spatial variation of nitrogen was simulated under different temperature conditions. Riverbank filtration is a natural aquifer-based process. The nitrogen dynamics in a riverbank filtration system are affected by many factors, including temperature, water quality, and travel time, which cannot be quantified easily. In this study, a field experiment was conducted to investigate nitrogen transport during riverbank filtration. The HYDRUS-2D software package was used to investigate and quantify the factors that affect the fate of nitrogen. The effects of temperature, water quality, and travel time on nitrate transport were considered. The model was calibrated and validated using field experimental data from the river water and groundwater during riverbank filtration at different periods. The results showed that HYDRUS-2D adequately simulated nitrate transport during riverbank filtration. The denitrification rate constant exhibited a positive exponential relationship with temperature. An empirical formula describing this relationship in riverbank filtration was developed and validated. In addition, the denitrification rate can be quantified within a specified temperature data range under field conditions. Compared with indoor experimental conditions, for the same temperature, there was a 10-fold increase in the denitrification rate constant under field conditions. The results showed that most of the nitrate removal occurred in the riparian zone at high temperatures during riverbank filtration. We concluded that the fate of nitrate in the riparian zone is strongly controlled by groundwater temperature. Travel time also plays an important role in nitrate removal during riverbank filtration.