Electrodeposition of HAp coatings on Ti6Al4V alloy and its electrochemical behavior in simulated body fluid solution

Hydroxyapatite (HAp) coatings were prepared on Ti6Al4V substrate by electrodeposition method from electrolyte solution containing Ca(NO₃)₂, NH₄H₂PO₄ and NaNO₃. The results show that the HAp coatings were single phase crystals of HAp. Scanning electron microscope (SEM) images present that HAp/Ti6Al4V have flake shapes which arrange to form like-coral agglomerates. In vitro test of the Ti6Al4V and HAp/Ti6Al4V in simulated body fluid (SBF) solution was investigated with different immersion times. pH of SBF solution decreased and the mass of materials increased. SEM images prove the formation of apatite on the surface of Ti6Al4V and HAp/Ti6Al4V. The corrosion current density during immersion time of substrate is always higher than the one of HAp/Ti6Al4V because the deposited HAp can protect well for the substrate. (paper)