Published January 12, 2007 | Version v1
Journal article

Length-Scale-Dependent Relaxation in Colloidal Gels

  • 1. Dipartimento di Scienze Fisiche, Universita di Napoli 'Federico II', 80125 Naples (Italy)
  • 2. Laboratoire des Colloiedes, Verres et Nanomateriaux, UMR5587 CNRS, Universite Montpellier 2, 34095 Montpellier (France)

Description

We use molecular dynamics computer simulations to investigate the relaxation dynamics of a simple model for a colloidal gel at a low volume fraction. We find that due to the presence of the open spanning network this dynamics shows at low temperature a nontrivial dependence on the wave vector which is very different from the one observed in dense glass-forming liquids. At high wave vectors the relaxation is due to the fast cooperative motion of the branches of the gel network, whereas at low wave vectors the overall rearrangements of the heterogeneous structure produce the relaxation process

Additional details

Publishing Information

Journal Title
Physical Review Letters
Journal Volume
98
Journal Issue
2
Journal Page Range
p. 028303-028303.4
ISSN
0031-9007
CODEN
PRLTAO

INIS

Country of Publication
United States
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
38024567
Subject category
S71: CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS; S36: MATERIALS SCIENCE; S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
COMPUTERIZED SIMULATION; GELS; GLASS; LIQUIDS; MOLECULAR DYNAMICS METHOD; RELAXATION; VECTORS
Descriptors DEC
CALCULATION METHODS; COLLOIDS; DISPERSIONS; FLUIDS; SIMULATION; TENSORS

Optional Information

Notes
(c) 2007 The American Physical Society