Published September 2018 | Version v1
Journal article

Speed-dependent Voigt lineshape parameter database from dual frequency comb measurements at temperatures up to 1305 K. Part II: Argon-broadened H2O absorption, 6801–7188 cm−1

  • 1. Precision Laser Diagnostics Laboratory, University of Colorado Boulder (United States)
  • 2. Jet Propulsion Laboratory – NASA, California Institute of Technology, 4800, Oak Grove Drive, Pasadena, CA 91109-8099 (United States)
  • 3. Applied Physics Division, National Institute of Standards and Technology, Boulder, CO (United States)

Description

Highlights: • We study 487 transitions of water vapor perturbed by Argon in the spectral range 6801–7188 cm−1 from 296–1305 K and 100–600 Torr. • We report 487 argon-broadening coefficients, 202 argon-broadening temperature-dependence exponents, and 353 speed-dependence coefficients. • We further report 448 argon-shift coefficients, and 220 argon-shift temperature-dependence exponents. • We present figures and trend equations to facilitate the use of this data beyond the spectral range explored. We report argon-broadened water vapor transition parameters and their temperature dependence based on measured spectra spanning 6801–7188 cm−1 from a broad-bandwidth, high-resolution dual frequency comb spectrometer. The 25 collected spectra of 2% water vapor in argon ranged from 296 K to 1305 K with total pressure spanning 100 Torr to 600 Torr. A multispectrum fitting routine was used in conjunction with a quadratic speed-dependent Voigt profile to extract broadening and shift parameters, and a power-law temperature-dependence exponent for both. The measurements represent the first broad bandwidth, argon-broadened water vapor absorption study, and are an important step toward a foreign-gas-perturbed, high-temperature database developed using advanced lineshape profiles.

Availability note (English)

Available from http://dx.doi.org/10.1016/j.jqsrt.2018.05.040

Additional details

Identifiers

DOI
10.1016/j.jqsrt.2018.05.040;
PII
S0022407318300025;

Publishing Information

Journal Title
Journal of Quantitative Spectroscopy and Radiative Transfer
Journal Volume
217
Journal Page Range
p. 189-212
ISSN
0022-4073
CODEN
JQSRAE

INIS

Country of Publication
United Kingdom
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
53005535
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
ABSORPTION; ABSORPTION SPECTROSCOPY; ARGON; EQUATIONS; RESOLUTION; SPECTRA; SPECTROMETERS; TEMPERATURE DEPENDENCE; VELOCITY; WATER VAPOR
Descriptors DEC
ELEMENTS; FLUIDS; GASES; MEASURING INSTRUMENTS; NONMETALS; RARE GASES; SORPTION; SPECTROSCOPY; VAPORS

Optional Information

Copyright
Copyright (c) 2018 Elsevier Ltd. All rights reserved.