Published 1982 | Version v1
Journal article Metadata-only

Atomic structure of KTc2(CH3COO)4Cl2 crystals

Creators

  • 1. AN SSSR, Moscow. Inst. Obshchej i Neorganicheskoj Khimii

Description

The structure of KTc2(CH3COO)4Cl2 crystals has been studied. The crystals are tetragonal (a=11.9885(3), c=11.2243(2) A, sp. gr. p42/n, Z=4) and they consist of dimer anions [Tc2(CH3COO)4Cl2]- and potassium cations. In the dimer technetium atom is bonded by aliquot bond with another technetium atom (2.1260(5) A), four oxygen atoms (2.065-2.089 A) of bridge acetate groups as well as with chlorine atom (2.589 (1) A) which is an axial ligand

Additional details

Additional titles

Original title (Russian)
Атомное строение кристаллов соединения KTc

Publishing Information

Journal Title
Koord. Khim.
Journal Volume
8
Journal Issue
6
Series
Koord. Khim.
Journal Page Range
851-854
ISSN
0132-344X

INIS

Country of Publication
Russian Federation
Country of Input or Organization
USSR
INIS RN
14770962
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
ACETATES; BOND ANGLE; BOND LENGTHS; CHLORIDES; DIMERS; LATTICE PARAMETERS; POTASSIUM COMPOUNDS; SPACE GROUPS; TECHNETIUM COMPLEXES; TETRAGONAL LATTICES
Descriptors DEC
ALKALI METAL COMPOUNDS; CARBOXYLIC ACID SALTS; CHLORINE COMPOUNDS; COMPLEXES; CRYSTAL LATTICES; CRYSTAL STRUCTURE; HALIDES; HALOGEN COMPOUNDS; SYMMETRY GROUPS; TRANSITION ELEMENT COMPLEXES