Published January 1986 | Version v1
Journal article Metadata-only

Isotope effect of reaction of cumyl peroxy radical with benzaldehyde

Creators

  • 1. AN Ukrainskoj SSR, Donetsk. Inst. Fiziko-Organicheskoj Khimii i Uglekhimii

Description

Cumyl cooxidation with benzaldehyde and its deuteroanalogs is studied using the method of small additions in the temperature range 338-358 K. By means of experimental data extrapolation to 298 K the values of isotopic effect Ksup(H)/Ksup(D) approximately 30 and the differences of activation energies observed Esup(D)-Esup(H)=6.7 kJ/mol are used

Additional details

Additional titles

Original title (Russian)
Изотопный эффект реакции кумилпероксирадикала с бензальдегидом

Publishing Information

Journal Title
Kinet. Katal.
Journal Volume
27
Journal Issue
1
Series
Kinet. Katal.
Journal Page Range
219-221
ISSN
0453-8811
CODEN
KNKTA

INIS

Country of Publication
Russian Federation
Country of Input or Organization
USSR
INIS RN
18001295
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
ACTIVATION ENERGY; BENZALDEHYDE; CHEMICAL REACTION KINETICS; DEUTERIUM; DEUTERIUM COMPOUNDS; ISOTOPE EFFECTS; OXIDATION; PEROXY RADICALS
Descriptors DEC
ALDEHYDES; CHEMICAL REACTIONS; ENERGY; HYDROGEN COMPOUNDS; HYDROGEN ISOTOPES; ISOTOPES; KINETICS; LIGHT NUCLEI; NUCLEI; ODD-ODD NUCLEI; ORGANIC COMPOUNDS; RADICALS; REACTION KINETICS; STABLE ISOTOPES

Optional Information

Notes
For English translation see the journal Kinetics and Catalysis (USA).