Published March 1991
| Version v1
Journal article
Kinetics study of radiation graft co-polymerization of styrene onto polyvinyl fluoride films
- 1. Inst. of Applied Technical Physics, Zhejiang Province (China)
Description
Radiation-induced graft copolymerization of styrene onto polyvinyl fluoride films was carried out by the 60Co-γ ray irradiation technique. The correlations of the rate of grafting with monomer concentration, dose rate of irradiation, film thickness and reaction temperature were studied and the rate of grafting was found to be proportional exponentially to the above former three parameters with index of 2.5, 0 and -1, respectively under the experimental conditions. The total activation energy of graft co-polymerization was determined to be 141.8 kJ/mol
Additional details
Publishing Information
- Journal Title
- Nuclear Techniques
- Journal Volume
- 14
- Journal Issue
- 3
- Series
- Nucl. Tech.
- Journal Page Range
- 183-187
- ISSN
- 0253-3219
- CODEN
- NUTED
INIS
- Country of Publication
- China
- Country of Input or Organization
- China
- INIS RN
- 23029936
- Subject category
- S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
- Descriptors DEI
- ACTIVATION ENERGY; COBALT 60; COPOLYMERIZATION; DOSE RATES; FLUORINE; GRAFT POLYMERS; IRRADIATION; POLYETHYLENES; RADIATION CHEMISTRY; REACTION KINETICS; SAMPLE PREPARATION; STYRENE; TEMPERATURE DEPENDENCE; THICKNESS
- Descriptors DEC
- AROMATICS; BETA DECAY RADIOISOTOPES; BETA-MINUS DECAY RADIOISOTOPES; CHEMICAL REACTIONS; CHEMISTRY; COBALT ISOTOPES; DIMENSIONS; ELEMENTS; ENERGY; HALOGENS; HYDROCARBONS; INTERMEDIATE MASS NUCLEI; INTERNAL CONVERSION RADIOISOTO; ISOMERIC TRANSITION ISOTOPES; ISOTOPES; KINETICS; MINUTES LIVING RADIOISOTOPES; NONMETALS; NUCLEI; ODD-ODD NUCLEI; ORGANIC COMPOUNDS; ORGANIC POLYMERS; POLYMERIZATION; POLYMERS; POLYOLEFINS; RADIOISOTOPES; YEARS LIVING RADIOISOTOPES