Published May 20, 2015
| Version v1
Journal article
The Reversible Magnesiation of Pb
Description
Sputtered Pb films have been found to reversibly alloy electrochemically with magnesium in Grignard based electrolytes. The voltage curve shows a single plateau at about 125 mV vs. Mg, corresponding to the formation of Mg2Pb, as confirmed by ex-situ X-ray diffraction. Pb was found to be the highest energy density Mg alloy yet reported, with the lowest voltage and highest volumetric capacity of any Mg alloy
Availability note (English)
Available from http://dx.doi.org/10.1016/j.electacta.2015.03.006Additional details
Identifiers
- DOI
- 10.1016/j.electacta.2015.03.006;
- PII
- S0013-4686(15)00576-9;
Publishing Information
- Journal Title
- Electrochimica Acta
- Journal Volume
- 165
- Journal Page Range
- p. 162-165
- ISSN
- 0013-4686
- CODEN
- ELCAAV
INIS
- Country of Publication
- United Kingdom
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 47036794
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- ALLOYS; ANODES; ELECTRIC POTENTIAL; ELECTROCHEMISTRY; ELECTROLYTES; ENERGY DENSITY; FILMS; MAGNESIUM; SPUTTERING; X-RAY DIFFRACTION
- Descriptors DEC
- ALKALINE EARTH METALS; CHEMISTRY; COHERENT SCATTERING; DIFFRACTION; ELECTRODES; ELEMENTS; METALS; SCATTERING
Optional Information
- Copyright
- Copyright (c) 2015 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.