Published May 2006 | Version v1
Journal article Metadata-only

Reactions in the M(HCOO)2-CS(NH2)2-H2O (M=Mg, Mn, Cd) system at 25 Deg C

Creators

  • 1. Inst. Obshchej i Neorganicheskoj Khimii Bolgarskoj Akademii Nauk, Sofiya (Bulgaria)
  • 2. Yugo-Zapadnyj Univ. Neofit Ril'skij, Blagoevgrad (Bulgaria)

Description

Complexing in the M(HCOO)2-CS(NH2)2-H2O (M=Mg, Mn, Cd) systems were studied by isothermal solubility at 25 Deg C. The compound (CdHCOO)2-CS(NH2)2-H2O was investigated by X-ray diffraction and IR-spectroscopy. Formation of the congruently soluble compound Cd(HCOO)2·2CS(NH2)2 is established in the Cd(HCOO)2-CS(NH2)2-H2O system, concentration limits of formation is determined, crystals belong to orthorhombic syngony

Abstract (Russian)

Методом изотермической растворимости изучено комплексообразование в системах M(HCOO)2-CS(NH2)2-H2O (M=Mg, Mn, Cd) при 25 град С. Соединение (CdHCOO)2-CS(NH2)2-H2O исследовано методами рентгенофазового анализа и ИК-спектроскопии. В системе Cd(HCOO)2-CS(NH2)2-H2O установлено образование конгруэнтно растворимого соединения Cd(HCOO)2·2CS(NH2)2, определены концентрационные границы образования, кристаллы относятся к орторомбической сингонии

Additional details

Additional titles

Original title (Russian)
Взаимодействие в системах М(HCOO)

Publishing Information

Journal Title
Zhurnal Neorganicheskoj Khimii
Journal Volume
51
Journal Issue
5
Journal Page Range
p. 880-884
ISSN
0044-457X
CODEN
ZNOKAQ

INIS

Country of Publication
Russian Federation
Country of Input or Organization
Russian Federation
INIS RN
37094545
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
CADMIUM COMPOUNDS; CHEMICAL COMPOSITION; COMPLEXES; FORMATES; INFRARED SPECTRA; ISOTHERMAL PROCESSES; ORTHORHOMBIC LATTICES; SOLUBILITY; TEMPERATURE RANGE 0273-0400 K; THIOUREAS; X-RAY DIFFRACTION
Descriptors DEC
CARBONIC ACID DERIVATIVES; CARBOXYLIC ACID SALTS; COHERENT SCATTERING; CRYSTAL LATTICES; CRYSTAL STRUCTURE; DIFFRACTION; ORGANIC COMPOUNDS; ORGANIC SULFUR COMPOUNDS; SCATTERING; SPECTRA; TEMPERATURE RANGE

Optional Information

Notes
36 refs., 2 figs., 5 tabs.