Published October 1993 | Version v1
Journal article

Oxyperoxovanadium (5) complexes with pyridine-2-carboxylate ion and o-phenanthroline. Features of coordination of bidentate chelate ligands in vanadium (5) oxoperoxocompounds

  • 1. AN SSSR, Moscow (Russian Federation). Inst. Obshchej i Neorganicheskoj Khimii

Description

Three compounds PPh4[VO(O2)Pic2]x2.5H2O (1), [VO(O2)PicPhen]x0.5CH2Cl2 (2) and [VO(O2)Phen(H2O)]Clx0.38H2O (3) were syntesized to study mutual effect of ligands in pseudooctahedric oxoperoxocomplexes of vanadium (5). Using complexes 1-3 by way of example and comparing them with other vanadium (5) oxomonoperoxocompounds studied, which contain bidentate chelate ligands, specific features of arrangement of the latter in the inner sphere of the like complexes are discussed

Additional details

Additional titles

Original title (Russian)
Комплексы оксопероксованадия (5) с пиридин-2-карбоксилат-ионом и о-фенантролином, особенности координации бидентатных хелатных лигандов в оксопероксосоединениях ванадия (5)

Publishing Information

Journal Title
Koordinatsionnaya Khimiya
Journal Volume
19
Journal Issue
10-11
Journal Page Range
p. 782-785.
ISSN
0132-344X
CODEN
KOKHDC