Published July 18, 1978
| Version v1
Patent
Method for improving the extraction properties of a tributyl phosphate solution
Description
Improvements to the Purex process are described, comprising contacting tributyl phosphate solution containing degradation products with a solution of diazomethane whereby the degradation products of tributyl phosphate are esterified to triesters having improved extraction properties. Thus a method has been developed which is relatively inexpensive, free from interfering by-products and side reactions and by which the extraction system is restored to almost its original efficiency. In addition, by this method, expensive cleanup procedures are eliminated and the use-life of the extraction solution is greatly prolonged
Availability note (English)
Available from Commissioner of Patents, Ottawa-Hull, Canada K1A 0E1.Additional details
Publishing Information
- Imprint Pagination
- 10 p.
- IPC:
- Int. Cl. C22B 60/02, B01J 1/22.
- IPC
- Int. Cl. C22B 60/02, B01J 1/22.
- Patent number
- CA patent document 1034769/A/
INIS
- Country of Publication
- Canada
- Country of Input or Organization
- Canada
- INIS RN
- 10425799
- Subject category
- S11: NUCLEAR FUEL CYCLE AND FUEL MATERIALS;
- Resource subtype / Literary indicator
- Non-conventional Literature
- Descriptors DEI
- DIAZO COMPOUNDS; ESTERIFICATION; OPTIMIZATION; PUREX PROCESS; RADIOLYSIS; TBP
- Descriptors DEC
- BUTYL PHOSPHATES; CHEMICAL RADIATION EFFECTS; CHEMICAL REACTIONS; DECOMPOSITION; ESTERS; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; ORGANIC PHOSPHORUS COMPOUNDS; PHOSPHORIC ACID ESTERS; RADIATION EFFECTS; REPROCESSING; SEPARATION PROCESSES