Published 1983
| Version v1
Journal article
Time resolved ESR spectroscopy
Creators
- 1. Akademie der Wissenschaften der DDR, Leipzig. Zentralinstitut fuer Isotopen- und Strahlenforschung
Description
Time resolved ESR experiments allow the study of the chemical kinetics as well as spin dynamics of free radicals in the liquid phase. Starting from the physical and chemical requirements the experimental parameters of a universal time resolved ESR spectrometer are derived. The main components of the ESR pulse radiolysis equipment are described and their technical parameters are discussed. By two experimental examples it is shown that at a time resolution of 0.3 μs a sensitivity of c/sub min/ = 10-6 mol dm-3 for simple radical spectra can be achieved. (author)
Additional details
Additional titles
- Subtitle (English)
- ESR pulse radiolysis equipment with microsecond time resolution
- Original title (German)
- Zeitaufloesende ESR-Spektroskopie
- Original subtitle (German)
- ESR-Pulsradiolyse-Apparatur mit Mikrosekunden-Zeitaufloesung.
Publishing Information
- Journal Title
- Exp. Tech. Phys.
- Journal Volume
- 31
- Journal Issue
- 5
- Series
- Exp. Tech. Phys.
- Journal Page Range
- 397-406
- ISSN
- 0014-4924
INIS
- Country of Publication
- Germany
- Country of Input or Organization
- German Democratic Republic
- INIS RN
- 15046030
- Subject category
- S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
- Descriptors DEI
- CHEMICAL REACTION KINETICS; ELECTRON SPIN RESONANCE; EPR SPECTROMETERS; LASER RADIATION; PULSE TECHNIQUES; RADICALS; RADIOLYSIS; SPECIFICATIONS; TIME RESOLUTION
- Descriptors DEC
- CHEMICAL RADIATION EFFECTS; CHEMICAL REACTIONS; DECOMPOSITION; ELECTROMAGNETIC RADIATION; KINETICS; MAGNETIC RESONANCE; MEASURING INSTRUMENTS; RADIATION EFFECTS; RADIATIONS; REACTION KINETICS; RESOLUTION; RESONANCE; SPECTROMETERS; TIMING PROPERTIES