Published November 2018
| Version v1
Journal article
Structural Features And Properties of Heteronuclear Germanium(IV) and Some 3d Metal Complexes with Xylaric Acid and 2,2′-Bipyridine
Creators
- 1. Mechnikov Odessa National University (Ukraine)
- 2. National Academy of Sciences of Ukraine, Scientific Technological Complex "Institute for Single Crystals" (Ukraine)
Description
New coordination compounds of germanium and 3d metals with xylaric acid (H5Xylar) and 2,2′-bipyridine (bipy), which contain tetranuclear xylaratogermanate anion [Fe(bipy)3]2[(OH)2Ge2(μ-HXylar)4Ge2(μ- OH)2]·12H2O·2CH3CN (I) and [Ni(bipy)3]2[(OH)2Ge2(μ-HXylar)4Ge2(μ-OH)2]·20H2O·2C2H5OH (II) are synthesized. The complexes are studied by the elemental analysis, thermogravimetry, IR spectroscopy, and X-ray diffraction. To visualize and quantitatively assess hydrogen bonds in I and II the Hiershfeld surface analysis is used.
Additional details
Identifiers
Publishing Information
- Journal Title
- Journal of Structural Chemistry
- Journal Volume
- 59
- Journal Issue
- 6
- Journal Page Range
- p. 1462-1468
- ISSN
- 0022-4766
- CODEN
- JSTCAM
INIS
- Country of Publication
- United States
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 55026453
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- ANIONS; BIPYRIDINES; CARBON NITRIDES; CRYSTAL STRUCTURE; CYANIDES; INFRARED SPECTRA; SURFACES; THERMAL GRAVIMETRIC ANALYSIS; X-RAY DIFFRACTION
- Descriptors DEC
- AZINES; CARBON COMPOUNDS; CHARGED PARTICLES; CHEMICAL ANALYSIS; COHERENT SCATTERING; DIFFRACTION; GRAVIMETRIC ANALYSIS; HETEROCYCLIC COMPOUNDS; IONS; NITRIDES; NITROGEN COMPOUNDS; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; PNICTIDES; PYRIDINES; QUANTITATIVE CHEMICAL ANALYSIS; SCATTERING; SPECTRA; THERMAL ANALYSIS
Optional Information
- Copyright
- Copyright (c) 2018 Pleiades Publishing, Ltd.