Published 1991 | Version v1
Journal article Metadata-only

Synthesis, crystal and molecular structures of the complex neptunium (5) sulfate, Cs3[NpO2(SO4)2]·2H2O

Creators

Description

Complex neptunium (5) sulfate was synthesized by evaporation at 27 deg C of (NpO2)2SO4 saturated solution in 1.5 mol/l of Cs2SO4. Its unit cell parameters were calculated. Np-O distances in NpO2+ are 182.3(4) and 181.7(4) pm. [NpO2(SO4)2]n3n- anion chain differs from the known ones for uranyl sulfates. Water is not included in Np coordination sphere

Additional details

Additional titles

Original title (Russian)
Синтез, кристаллическая и молекулярная структуры комплексного сульфата нептуния (5) Cс

Publishing Information

Journal Title
Radiokhimiya
Journal Volume
33
Journal Issue
2
Series
Radiokhimiya.
Journal Page Range
17-19
ISSN
0033-8311
CODEN
RADKA

INIS

Country of Publication
Russian Federation
Country of Input or Organization
USSR
INIS RN
23041630
Subject category
S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
Descriptors DEI
CESIUM COMPOUNDS; CHEMICAL PREPARATION; CRYSTAL STRUCTURE; HYDRATES; INTERATOMIC DISTANCES; LATTICE PARAMETERS; MOLECULAR STRUCTURE; NEPTUNYL COMPLEXES; SULFATES
Descriptors DEC
ACTINIDE COMPLEXES; ALKALI METAL COMPOUNDS; COMPLEXES; DISTANCE; NEPTUNIUM COMPLEXES; OXYGEN COMPOUNDS; SULFUR COMPOUNDS; SYNTHESIS; TRANSURANIUM COMPLEXES