Published August 30, 2010 | Version v1
Journal article

Raman spectroscopy and Fermi resonance in Mn-doped ZnO bulk single crystal

  • 1. Institute of Spectroscopy of RAS, Fizicheskaya, 5, Troitsk Moscow reg., 142190 (Russian Federation)
  • 2. Institute of Crystallography of RAS, Leninsky pr. 59, Moscow, 119333 (Russian Federation)

Description

For the first time the bulk oriented single crystals ZnO:Mn are obtained and the polarized Raman spectra are studied at excitation in the visible and near infrared regions. The resonance enhancing of the Raman scattering by Mn-related modes is found at the visible excitation due to the extra optical absorption in ZnO at the addition of Mn. It is shown that the resonance-enhanced overtone of Mn-related silent modes may be responsible for an appearance of anomalous modes of the A1 symmetry at 500-600 cm-1. A Fermi resonance between the overtone and one-phonon mode is analyzed.

Availability note (English)

Available from http://dx.doi.org/10.1016/j.physleta.2010.06.045

Additional details

Identifiers

DOI
10.1016/j.physleta.2010.06.045;
PII
S0375-9601(10)00731-0;

Publishing Information

Journal Title
Physics Letters. A
Journal Volume
374
Journal Issue
39
Journal Page Range
p. 4054-4056
ISSN
0375-9601
CODEN
PYLAAG

Optional Information

Copyright
Copyright (c) 2010 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.