Published April 1978
| Version v1
Journal article
Study of interaction in systems of MoCl5-MeCl2 (Me - Sn, Zn, Cd, Hg) - a solvent
Creators
- 1. Kievskij Gosudarstvennyj Univ. (Ukrainian SSR)
Description
Interaction of Mo(5) with dichlorides of tin, zinc, cadmium and mercury in organic solvents was studied by preparative methods, by electron, epr, infrared spectrometry and by conductometry. A polynuclear diamagnetic compound with Mo(5):Sn(2) ratio of 2:1 formed in acetone. A coordination polynuclear compound of (MoOCl3)2xSnCl2x2CH3CN was isolated from acetonitryl. It is shown that formation of solvate-chloride and solvate complexes of No(5) in solvents depends both on the solvating capacity of the solvent and on stability of the MeCl-3 (Me is Sn, Zn, Cd, Hg) chloride complex, which grows in the Zn < Sn < Cd < Hg series
Additional details
Additional titles
- Original title (Russian)
- Изучение взаимодействия в системах MoCl
Publishing Information
- Journal Title
- Ukr. Khim. Zh.
- Journal Volume
- 44
- Journal Issue
- 4
- Series
- Ukr. Khim. Zh.
- Journal Page Range
- 352-355
INIS
- Country of Publication
- USSR
- Country of Input or Organization
- USSR
- INIS RN
- 10420288
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- CHEMICAL REACTIONS; ELECTRON SPECTRA; ELECTRON SPIN RESONANCE; INFRARED SPECTRA; MOLYBDENUM CHLORIDES; MOLYBDENUM COMPLEXES; ORGANIC SOLVENTS; TIN CHLORIDES
- Descriptors DEC
- CHLORIDES; CHLORINE COMPOUNDS; COMPLEXES; HALIDES; HALOGEN COMPOUNDS; MAGNETIC RESONANCE; MOLYBDENUM COMPOUNDS; NONAQUEOUS SOLVENTS; RESONANCE; SOLVENTS; SPECTRA; TIN COMPOUNDS; TRANSITION ELEMENT COMPLEXES; TRANSITION ELEMENT COMPOUNDS
Optional Information
- Notes
- For English translation see the journal Sov. Prog. Chem.