Published September 1994
| Version v1
Journal article
Synthesis and X-ray structure determination of N,N'-bis-l-(1-carboxy-2-mercaptoethyl)ethylenediamine,oxotechnetiu m(V), [TcO(EC)]
Creators
- 1. National Research Centre for the Physical Sciences Democritos, Athens (Greece)
Description
The complex of N,N'-bis-1-(carboxy-2-mercaptoethyl)ethylene-diamine (EC) labelled with reduced Tc-99m was proposed as a new agent in renal tubular secretion studies. Here we present the synthesis and single-crystal X-ray structure determination of the N,N'-bis-1-(1-carboxy-2-mercaptoethyl)ethylene-diamine oxotechnetium(V) complex, [99TcO(EC)]. The technetium is hexacoordinated being bonded to oxygen (1.657(3)A), the two N atoms and the two deprotonated S atoms. The sixth site, trans to the oxo-group is occupied by one deprotonated carboxylate group. The infrared spectra is also presented. (author)
Additional details
Publishing Information
- Journal Title
- Journal of Labelled Compounds and Radiopharmaceuticals
- Journal Volume
- 34
- Journal Issue
- 9
- Journal Page Range
- p. 817-829.
- ISSN
- 0362-4803
- CODEN
- JLCRD4
INIS
- Country of Publication
- United Kingdom
- Country of Input or Organization
- United Kingdom
- INIS RN
- 26028191
- Subject category
- S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
- Descriptors DEI
- AMINES; CHEMICAL PREPARATION; KIDNEYS; LABELLING; RADIOPHARMACEUTICALS; STRUCTURAL CHEMICAL ANALYSIS; TECHNETIUM COMPLEXES; TECHNETIUM 99; THIOLS; X-RAY DIFFRACTION
- Descriptors DEC
- BETA DECAY RADIOISOTOPES; BETA-MINUS DECAY RADIOISOTOPES; BODY; COHERENT SCATTERING; COMPLEXES; DIFFRACTION; DRUGS; HOURS LIVING RADIOISOTOPES; INTERMEDIATE MASS NUCLEI; INTERNAL CONVERSION RADIOISOTOPES; ISOMERIC TRANSITION ISOTOPES; ISOTOPES; LABELLED COMPOUNDS; MATERIALS; NUCLEI; ODD-EVEN NUCLEI; ORGANIC COMPOUNDS; ORGANIC SULFUR COMPOUNDS; ORGANS; RADIOACTIVE MATERIALS; RADIOISOTOPES; SCATTERING; SYNTHESIS; TECHNETIUM ISOTOPES; TRANSITION ELEMENT COMPLEXES; YEARS LIVING RADIOISOTOPES