Published January 1987
| Version v1
Journal article
Crystal, molecular structure, and magnetic properties of bis-[4-(2'-oxo-3',3',3'-trifluopropylidenyl)-2,2,5,5-tetramethyl-3-imidazolin-1-oxyl] copper(II) Cu(C10H13F3N2O2)2
Description
The crystal structure of the complex of copper(II) with the paramagnetic ketone 4-(2'-oxo-3',3',3'-trifluorpropylidenyl)-2,2,5,5-tetramethyl-3-imidazolin-1-oxyl has been determined and the statistical magnetic susceptibility of the polycrystalline material was measured by the Faraday method over a temperature range of 4.2-3000K. A theoretical interpretation of the magnetic properties of the coordination compound was carried out using an isotropic exchange model. The results of the calculations agree with the experiment
Additional details
Publishing Information
- Journal Title
- J. Struct. Chem. (Engl. Transl.)
- Journal Volume
- 27
- Journal Issue
- 4
- Series
- J. Struct. Chem. (Engl. Transl.).
- Journal Page Range
- 555-561
- ISSN
- 0022-4766
- CODEN
- JSTCA
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 19039671
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; S36: MATERIALS SCIENCE; S36: MATERIALS SCIENCE;
- Resource subtype / Literary indicator
- Translation
- Descriptors DEI
- ATOMIC MODELS; BOND ANGLE; BOND LENGTHS; CHELATES; COPPER COMPLEXES; ELECTRON TRANSFER; ELECTRONIC STRUCTURE; ENERGY LEVELS; ENERGY-LEVEL TRANSITIONS; FARADAY METHOD; HAMILTONIANS; IMIDAZOLES; LATTICE PARAMETERS; MAGNETIC MOMENTS; MAGNETIC SUSCEPTIBILITY; MOLECULAR STRUCTURE; ORGANIC FLUORINE COMPOUNDS; ORTHORHOMBIC LATTICES; PARAMAGNETISM; QUANTUM MECHANICS; SPIN; ULTRALOW TEMPERATURE; X-RAY DIFFRACTION
- Descriptors DEC
- ANGULAR MOMENTUM; AZOLES; COHERENT SCATTERING; COMPLEXES; CRYSTAL LATTICES; CRYSTAL STRUCTURE; DIFFRACTION; HETEROCYCLIC COMPOUNDS; MAGNETIC PROPERTIES; MAGNETISM; MATHEMATICAL MODELS; MATHEMATICAL OPERATORS; MECHANICS; ORGANIC COMPOUNDS; ORGANIC HALOGEN COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; PARTICLE PROPERTIES; PHYSICAL PROPERTIES; QUANTUM OPERATORS; SCATTERING; TRANSITION ELEMENT COMPLEXES
Optional Information
- Notes
- Translated from Zh. Strukt. Khim.; 27: No. 4, 61-68(Jul-Aug 1986).