Published November 2009 | Version v1
Journal article

Which orbital and charge ordering in transition metal oxides can resonant X-ray diffraction detect?

  • 1. Equipe de Physique des Surfaces et Interfaces, Institut de Physique de Rennes UMR UR1-CNRS 6251, Universite de Rennes 1, F-35042 Rennes Cedex (France)

Description

The present article is a brief critical review about the possibility of detecting charge and/or orbital order in transition-metal oxides by means of resonant x-ray diffraction. Many recent models of transition-metal oxides are based on charge and/or orbitally ordered ground-states and it has been claimed in the past that resonant x-ray diffraction is able to confirm or reject them. However, in spite of the many merits of this technique, such claims are ambiguous, because the interpretative frameworks used to analyze such results in transition-metal oxides, where structural distortions are always associated to the claimed charged/orbitally ordered transition, strongly influence (not to say suggest) the answer. In order to clarify this point, I discuss the two different definitions of orbital and charge orderings which are often used in the literature without a clear distinction. My conclusion is that the answer to the question of the title depends on which definition is adopted.

Availability note (English)

Available from http://dx.doi.org/10.1088/1742-6596/190/1/012008

Additional details

Publishing Information

Journal Title
Journal of Physics. Conference Series (Online)
Journal Volume
190
Journal Issue
1
Journal Page Range
[12 p.]
ISSN
1742-6596

Conference

Title
14. international conference on X-ray absorption fine structure
Acronym
XAFS14
Dates
26-31 Jul 2009
Place
Camerino (Italy)

INIS

Country of Publication
United Kingdom
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
42029997
Subject category
S75: CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; S74: ATOMIC AND MOLECULAR PHYSICS;
Resource subtype / Literary indicator
Conference
Descriptors DEI
GROUND STATES; OXIDES; RESONANCE SCATTERING; REVIEWS; TRANSITION ELEMENT COMPOUNDS; X-RAY DIFFRACTION
Descriptors DEC
CHALCOGENIDES; COHERENT SCATTERING; DIFFRACTION; DOCUMENT TYPES; ENERGY LEVELS; INELASTIC SCATTERING; OXYGEN COMPOUNDS; SCATTERING