Published December 15, 1988 | Version v1
Journal article

Structure of an ammonium molybdenyl diphosphate: (NH4)2MoO2P2O7

  • 1. Centre National de la Recherche Scientifique, 38 - Grenoble (France). Lab. de Cristallographie

Description

(NH4)2MoO2P2O7, Mr=333.925, monoclinic, C2/c, a=13.984 (9), b=8.297 (6), c=15.81 (1) A, β=99.11 (1)0, V=1811 (4) A3, Z=8, Dx=2.449 Mg m-3, λ(MoKαanti)=0.7107 A, μ=1.811 mm-1, F(000)=1296, T=295 K, final R=0.021 for 2728 independent observations. Isolated MoO6 distorted octahedra share four of their oxygen atoms with three different P2O7 groups to build infinite ribbons spreading along the c axis. The two oxygen atoms of the molybdenyl group remain unshared. Along the c axis, large oblong channels delimited by the MoO6-P2O7 ribbons are lined by the ammonium groups. (orig.)

Additional details

Publishing Information

Journal Title
Acta Crystallographica, Section C
Journal Volume
44
Journal Issue
12
Series
Acta Crystallogr., Sect. C.
Journal Page Range
2046-2048
ISSN
0108-2701
CODEN
ACSCE