Published March 1, 1979
| Version v1
Journal article
Photoionization of ethylene clusters
- 1. Materials and Molecular Research Division, Lawrence Berkeley Laboratory and Department of Chemistry, University of California, Berkeley, California 94720
Description
The energetics of the ethylene ion--molecule reactions has been investigated in more detail than previously possible in two body collision experiments by photoionization of the neutral van der Waals ethylene dimer. The stability of the ion--molecule collision complex (18.2 +- 0.5 kcal) as well as the highest potential barrier along the reaction coordinate for decomposition have been determined for this exothermic reaction. In a similar manner, the energetics of the solvated ethylene ion has been investigated by photoionization of the ethylene trimer
Additional details
Publishing Information
- Journal Title
- J. Chem. Phys.
- Journal Volume
- 70
- Journal Issue
- 5
- Series
- J. Chem. Phys.
- Journal Page Range
- 2138-2144
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 10463959
- Subject category
- S74: ATOMIC AND MOLECULAR PHYSICS;
- Resource subtype / Literary indicator
- Numerical Data
- Descriptors DEI
- DIMERS; ETHYLENE; EXPERIMENTAL DATA; ION-MOLECULE COLLISIONS; ISOLATED VALUES; PHOTOIONIZATION; POLYMERS; SOLVATION; TWO-BODY PROBLEM; VAN DER WAALS FORCES
- Descriptors DEC
- ALKENES; COLLISIONS; DATA; DATA FORMS; HYDROCARBONS; INFORMATION; ION COLLISIONS; IONIZATION; MANY-BODY PROBLEM; MOLECULE COLLISIONS; NUMERICAL DATA; ORGANIC COMPOUNDS