Published 1977
| Version v1
Journal article
Preparational, structural and vibrational study of M2U2O5Cl4, 2H2O(M = Rb,Cs). Detection of a tetranuclear anion [(UO2)4O2Cl8(H2O)2]4-
Description
The interaction between M2UO2Cl4, nH2O (M = Rb,Cs) and UO2(OH)2 leads to new complexes M2U2O5Cl4, 2H2O: however, structural determination by X-ray diffraction exhibits discrete tetranuclear anions [(UO2)4O2Cl8(H2O)2]4-: uranyl groups are bonded together in their equatorial plane by O/O or O/Cl double bridges in which oxygen atom is tricoordinated with U-O (bridge) distances lying between 2.20 and 2.29 A. Vibrational spectra are recorded and interpreted and hydrogen bonds discussed. (author)
Additional details
Additional titles
- Original title (French)
- Preparation, etude structurale et vibrationnelle des complexes M
Identifiers
Publishing Information
- Journal Title
- Journal of Inorganic and Nuclear Chemistry
- Journal Volume
- 39
- Journal Issue
- 7
- Series
- J. Inorg. Nucl. Chem.
- Journal Page Range
- 1169-1172
- ISSN
- 0022-1902
INIS
- Country of Publication
- United Kingdom
- Country of Input or Organization
- United Kingdom
- INIS RN
- 8337074
- Subject category
- S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
- Descriptors DEI
- CHEMICAL BONDS; CHEMICAL PREPARATION; INFRARED SPECTRA; MOLECULAR STRUCTURE; RAMAN SPECTRA; URANYL COMPLEXES; X-RAY DIFFRACTION
- Descriptors DEC
- ACTINIDE COMPLEXES; COHERENT SCATTERING; COMPLEXES; DIFFRACTION; SCATTERING; SPECTRA; SYNTHESIS; URANIUM COMPLEXES
Optional Information
- Notes
- Updated automatically by Metadata and Full-Text Enrichment Agent