Published September 15, 1985
| Version v1
Journal article
Electronic interactions in metal-hydrogen solid solutions: ScH/sub x/, YH/sub x/, and V/sub 0.75/Nb/sub 0.25/H/sub x/
- 1. Department of Chemical Engineering and Materials Science, University of Minnesota, Minneapolis, Minnesota 55455
Description
The electronic interactions of hydrogen in a host metal lattice have been studied with synchrotron-radiation photoemission for low-x solid solution phases of ScH/sub x/, YH/sub x/, and V/sub 0.75/Nb/sub 0.25/H/sub x/ for 0.15< or =x< or =0.25. For each system, a single well-defined hydrogen-induced feature is observed 5 eV below the Fermi level due to the local interaction of H with bonding metal-derived states, in agreement with linear combination of atomic orbitals save no evidence for hydride formation induced by cleaving the α-phase hydride samples
Additional details
Publishing Information
- Journal Title
- Phys. Rev., B: Condens. Matter
- Journal Volume
- 32
- Journal Issue
- 6
- Series
- Phys. Rev., B: Condens. Matter.
- Journal Page Range
- 3562-3567
- ISSN
- 0163-1829
- CODEN
- PRMBD
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 17012162
- Subject category
- S36: MATERIALS SCIENCE;
- Descriptors DEI
- BINDING ENERGY; CHEMISORPTION; COMPARATIVE EVALUATIONS; ELECTRONIC STRUCTURE; HYDROGEN; INTERACTIONS; METALS; PHOTOEMISSION; QUANTITY RATIO; SOLID SOLUTIONS; SYNCHROTRON RADIATION
- Descriptors DEC
- BREMSSTRAHLUNG; CHEMICAL REACTIONS; DISPERSIONS; ELECTROMAGNETIC RADIATION; ELEMENTS; EMISSION; ENERGY; EVALUATION; HOMOGENEOUS MIXTURES; MIXTURES; NONMETALS; RADIATIONS; SECONDARY EMISSION; SEPARATION PROCESSES; SOLUTIONS