Published January 1988
| Version v1
Journal article
Interpreting the optical spectra of trace Fe2+ in layer silicates
Creators
- 1. Dumanskii Institute of Colloid and Water Chemistry (USSR)
Description
Estimates have been made of Fe2+ term splittings in axial crystalline fields. It is found that all three long-wave bands in the optical spectrum are due to Fe2+ α Fe3+ charge transfer, while the splitting of 5T/sub 2g/ and 5E/sub g/ occurs in low-symmetry fields. Experimental evidence is presented for these calculations
Additional details
Publishing Information
- Journal Title
- Theoretical and Experimental Chemistry (English Translation)
- Journal Volume
- 23
- Journal Issue
- 4
- Series
- Theor. Exp. Chem. (Engl. Transl.).
- Journal Page Range
- 435-438
- ISSN
- 0040-5760
- CODEN
- TEXCA
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 20048292
- Subject category
- S36: MATERIALS SCIENCE; S71: CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS;
- Resource subtype / Literary indicator
- Translation
- Descriptors DEI
- ABSORPTION SPECTRA; ELECTRON TRANSFER; ENERGY LEVELS; ENERGY-LEVEL TRANSITIONS; FINE STRUCTURE; HAMILTONIANS; IRON COMPOUNDS; IRON 57; JAHN-TELLER EFFECT; LINE WIDTHS; MOESSBAUER EFFECT; QUADRUPOLES; SILICATES; SYMMETRY; TRIPLETS; VISIBLE SPECTRA
- Descriptors DEC
- EVEN-ODD NUCLEI; INTERMEDIATE MASS NUCLEI; IRON ISOTOPES; ISOTOPES; MATHEMATICAL OPERATORS; MULTIPLETS; MULTIPOLES; NUCLEI; OXYGEN COMPOUNDS; QUANTUM OPERATORS; SILICON COMPOUNDS; SPECTRA; STABLE ISOTOPES; TRANSITION ELEMENT COMPOUNDS
Optional Information
- Notes
- Translated from Teoret. Eksper. Khimiya; 23: No. 4, 464-468(Jul-Aug 1987). Cover-to-cover translation of Teoreticheskaya i Ehksperimental'naya Khimiya (USSR).