Published 1978 | Version v1
Report Restricted

Diffraction pattern and models of liquid antimony trichloride

Description

Neutron and x-ray diffraction data for liquid SbCl3 at 800C are presented and discussed. The liquid consists of discrete molecules with an Sb-Cl distance of 2.35 A and a Cl-Sb-Cl angle of 960. The diffraction data are analyzed to yield structure and correlation functions for intermolecular Sb...Sb, Sb...Cl, and Cl...Cl interactions. These curves yield directly some valuable insight into the nature of the strong orientational correlations present in liquid SbCl3. The data are also used to test site-site interaction models for molecular fluids. The relative role of repulsive and attractive forces for the structure of liquid SbCl3 is discussed. 6 figures

Availability note (English)

MF available from INIS under the Report Number; Available from NTIS., PC A02/MF A01.

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Additional details

Publishing Information

Imprint Pagination
20 p.
Report number
CONF-780942--1

Conference

Title
Structure and motion in molecular liquids.
Dates
13 - 15 Sep 1978.
Place
Canterbury, UK.

INIS

Country of Publication
United States
Country of Input or Organization
United States
INIS RN
10436293
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Resource subtype / Literary indicator
Conference
Descriptors DEI
ANTIMONY CHLORIDES; BOND ANGLE; BOND LENGTHS; INTERATOMIC DISTANCES; LIQUIDS; MOLECULAR STRUCTURE; NEUTRON DIFFRACTION; X-RAY DIFFRACTION
Descriptors DEC
ANTIMONY COMPOUNDS; CHLORIDES; CHLORINE COMPOUNDS; COHERENT SCATTERING; DIFFRACTION; DISTANCE; FLUIDS; HALIDES; HALOGEN COMPOUNDS; SCATTERING