Published 1978
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Diffraction pattern and models of liquid antimony trichloride
Description
Neutron and x-ray diffraction data for liquid SbCl3 at 800C are presented and discussed. The liquid consists of discrete molecules with an Sb-Cl distance of 2.35 A and a Cl-Sb-Cl angle of 960. The diffraction data are analyzed to yield structure and correlation functions for intermolecular Sb...Sb, Sb...Cl, and Cl...Cl interactions. These curves yield directly some valuable insight into the nature of the strong orientational correlations present in liquid SbCl3. The data are also used to test site-site interaction models for molecular fluids. The relative role of repulsive and attractive forces for the structure of liquid SbCl3 is discussed. 6 figures
Availability note (English)
MF available from INIS under the Report Number; Available from NTIS., PC A02/MF A01.
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Additional details
Publishing Information
- Imprint Pagination
- 20 p.
- Report number
- CONF-780942--1
Conference
- Title
- Structure and motion in molecular liquids.
- Dates
- 13 - 15 Sep 1978.
- Place
- Canterbury, UK.
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 10436293
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Resource subtype / Literary indicator
- Conference
- Descriptors DEI
- ANTIMONY CHLORIDES; BOND ANGLE; BOND LENGTHS; INTERATOMIC DISTANCES; LIQUIDS; MOLECULAR STRUCTURE; NEUTRON DIFFRACTION; X-RAY DIFFRACTION
- Descriptors DEC
- ANTIMONY COMPOUNDS; CHLORIDES; CHLORINE COMPOUNDS; COHERENT SCATTERING; DIFFRACTION; DISTANCE; FLUIDS; HALIDES; HALOGEN COMPOUNDS; SCATTERING