Optical characterization, 1.5 μm emission and IR-to-visible energy upconversion in Er3+-doped fluorotellurite glasses

The optical properties of Er3+ ions in a novel glass based on TeO2-PbF2-AlF3 oxyfluoride tellurites have been investigated using steady-state and time-resolved spectroscopies as a function of the rare-earth doping concentration. Basic optical characterizations have been performed measuring and calculating the absorption and emission spectra and the cross-sections, the Judd-Ofelt intensity parameters, the radiative probabilities and the fluorescence decays and lifetimes. Special attention has been devoted to the broad 4I13/2→4I15/2 emission transition at around 1.53 μm since, with a wide broadening of around 70 nm and a relative long lifetime of around 3 ms compared to others glass hosts, it shows potential applications in the design of erbium-doped fiber amplifiers. The absorption, the stimulated emission and the gain cross-sections of this transition have been obtained and compared with that obtained in different hosts. Finally, infrared-to-visible upconversion processes exciting at around 800 nm have been analyzed and different mechanisms involved in the energy conversion have been proposed. - Research highlights: → Broadened emission bands and high absorption and emission cross-sections for the transition 4I15/2→4I13/2 suitable for EDFAs. → Efficient green upconverted emission. → High value of CDA(6) energy transfer parameter.