Published October 2019 | Version v1
Journal article

A fascinating multifunctional bis(2-(4,5-diphenyl-1H-imidazol-2-yl)phenoxy)nickel complex: An excellent electrode material for supercapacitor and uric acid sensor

  • 1. Department of Chemistry, Bishop Heber College, Tiruchirappalli, 620 017, Tamil Nadu (India)
  • 2. Department of Materials and Mineral Resources Engineering, National Taipei University of Technology, No.1, Section 3, Chung-Hsiao East Road, Taipei 106 (China)

Description

In the present work, nickel-trisubstituted imidazole complex, bis(2-(4,5-diphenyl-1H-imidazol-2-yl)phenoxy)nickel complex, abbreviated as NDIP was prepared by chemical method and its application as an electrode for supercapacitor was demonstrated. The structure and composition of the as-synthesized NDIP was confirmed by various spectral and analytical tools and further it was examined for its sensing and supercapacitor applications. NDIP coated working electrode delivered the specific capacitance of 712 F/g at the current density of 1 A/g and capacitance retention of 87% upto 2000 GCD cycles. The developed sensor was explored to detect Uric Acid. The response for amperometric detection of UA on NDIP displayed a wide linear range (0.1 nm – 1031 μM) with low detection limit (0.412 μM). Furthermore, NDIP@GCE electrode showed a high selectivity and good responsiveness towards UA detection.

Additional details

Identifiers

DOI
10.1016/j.materresbull.2019.05.007;
PII
S0025540819307986;

Publishing Information

Journal Title
Materials Research Bulletin
Journal Volume
118
Journal Page Range
vp.
ISSN
0025-5408
CODEN
MRBUAC

Optional Information

Copyright
Copyright (c) 2019 Elsevier Ltd. All rights reserved.